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HOJA DE SEGURIDAD ACIDO SULFONICO ELOTANT

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ELOTANT™ LS100
1. Chemical Product and Company Identification
a. Product name
ELOTANT LS100
Shampoo, soap, foam compositions, detergent raw
materials
b. Product use
c. Company Identification
LG Household & Healthcare Ltd.
LG GwangHwaMoon Building, 92, Sinmunno 2ga,Jongno-gu, Seoul South Korea Zip Code 110062
Tel : 82-505-305-7007
e-mail : [email protected]
Manufacturer
Emergency phone number
2. Hazard Identification
a. Classification of the substance or mixture
Corrosive to metal: 1 category
Acute toxicity : 4 category
Skin corrosion/irritation : 2 category
Serious eye damage/eye irritation : 1 category
Skin sensitizer : 1 category
Specific target organ toxicity following single
exposure: 2 category
b. GHS label elements, including precautionary statements
Signal words
Hazard statements
Precautionary statements
Prevention
Danger
H290 May be corrosive to metals
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause allergic skin reaction
H318 Causes serious eye damage
H371 May cause damage to organ
P234 Keep only in original container
P260 Do not breathe
dust/fume/gas/mist/vapor/sprays.
P261 Avoiding breathe
dust/fume/gas/mist/vapor/sprays.
1
Response
Storage
Disposal
c. Other hazards which do not result in classification
Health
Flammability
Reactivity
P264 Wash ….thoroughly after handling.
P270 Do not eat, drink or smoke when using this
product
P272 Contaminated work clothing should not be
allowed out of the workplace
P280 Wear protective gloves, protective clothing,
eye protection, fact protection
P301+P312 If swallowed: Call a poison center or
doctor/physician
P302+P352 Gently wash with plenty of soap and
water
P305+P351+p338 If in eyes Rinse cautiously with
water several minute
P309+P311 IF exposed or if you feel unwell: Call
a POISON CENTER or doctor/physician.
P310 Immediately call a poison center or
doctor/physician
P321 Specific treatment (see…. On this label)
P330 Rinse mouth
P332+P313 If skin irritation occurs, get medical
advice/ attention
P333+P313 If skin irritation or rash occurs
P405 Store locked up
P501 Dispose of containers/containers to…
3
1
0
3. Composition/information on ingredients
Component name
CAS Number
%(w/w)
Dodecyl benzene Sulfonic acid
27176-87-0
96 % min
Water
7732-18-5
2% max
4. First-aid measures
a. Eye contact
b. Skin contact
c. Inhalation
Wash Eyes Immediately With Large Amounts Of Water.
Get medical attention immediately.
Remove Contaminated Clothing Immediately.
Wash with Soap or Mild Detergent and Large Amounts of Water
Until No Evidence of Chemical Remains (At Least 15-20 Minutes).
Remove Contaminated Clothing Immediately.
Use a Bag Valve mask or Similar Device to Perform Artificial
Respiration (Rescue Breathing) If Needed.
Get Medical Attention Immediately.
2
d. Ingestion
e. Further medical
Contact Local Poison Control Center or Physician Immediately
Give Large Amounts of Water. Allow Vomiting to Occur.
N/A
5. Fire-fighting measures
a. Suitable extinguishing media
Suitable extinguishing media
Large fire
b. Specific hazards arising from the chemical
Products of heat decomposition
c. Special protective actions for fire-fighters
CO2
Regular dry chemical
Water
Dry powder
Fight larger fires with water spray or alcohol
resistant foam
Carbon oxide, Sulfur oxide
Wear self contained breathing apparatus and
protective gear.
6. Accidental release measures
a. Personal precautions, protective equipment
and emergency procedures
b. Environmental precautions
Air
Soil
underwater
c. Methods and materials for containment and cleaning up
Spill and releases
Contain the spilled liquid with sand or an inert
absorbent material.
Avoid all possible sources of ignition (halogen,
Spark, flame)
Transfer used material to a suitable waste
container and dispose of in accordance with local
regulation.
N/A
N/A
N/A
Wash residue from spill area with water
containing detergent and flush to a sewer
serviced by a permitted wastewater treatment
facility.
7. Handling and storage
a. Precautions for safe handling
b. Conditions for safe storage
Normal precautions should be observed as for
handling all chemicals.
Store in the original closed containers under dry
conditions.
Keep way from incompatibles such as oxidizing
agents, acids
Avoid all possible sources of ignition (halogen,
Spark, flame)
3
8. Exposure controls/personal protection
a. Control parameters
Internal regulation
ACGIH
Biological limit values
b. Appropriate engineering controls
c. Individual protection measures
Respiratory protection
Eye protection
Protective gloves
Skin protection
N/A
N/A
N/A
Provide exhaust ventilation.
Other engineering controls to keep the airborne
concentrations of vapors below their respective
threshold limit value.
Use vapor respirator
Use goggles
Wash eyes before breaks and at the end of
work.
Protective gloves
Protective work clothing
9. Physical and chemical properties
a. Appearance
Physical state
Color
b. Odor
c. Odor threshold
d. pH
e. Melting point/freezing point
f. Initial boiling and boiling range
g. Flash point
h. Evaporation rate
i. Flammability
j. Upper/lower flammability
k. Vapor pressure
l. Solubility
m. Vapor density
n. Relative density
o. Partition coefficient: n-octanol/water
p. Auto-ignition temperature
q. Decomposition temperature
r. Viscosity
s. Molecular weight
Liquid
Dark brown
Special odor
N/A
1~2
10℃
315℃
149℃
N/A
N/A
N/A
N/A
Soluble
N/A
1.053 at 25 ℃
N/A
N/A
N/A
950 cps at 25 ℃
326.54
4
10. Stability and Reactivity
a. Chemical stability & Possibility of hazardous
reactions
b. Condition to avoid
Stable in room temperature, no reaction.
c. Incompatible materials
Metals oxidizing materials, strong alkali,
peroxide materials
When combustion & burning, may occur
irritations and harmful gas.
d. Hazardous decomposition products
11. Toxicological information
Avoid heat, flames, sparks and other sources of
ignition
a. Information on the likely routes of exposures
Inhalation: N/A
Acute: N/A
Skin: N/A
Eyes: N/A
b. Symptoms related to physical, chemical and toxicological characteristics
Acute toxicity
Oral
LD 50 650mg/kg Rat
Thermal
N/A
Gases
N/A
Skin corrosion & irritation
2 Category
Serious eye damage/eye irritation
1 Category
Respiratory
N/A
Skin sensitization
Slightly irritation
Carcinogenicity
IARC
NTP
OSHA
WISHA
ACGIH
Germ cell mutagenicity
Reproductive toxicity
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Aspiration hazard
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
12. Ecological information
a. Eco toxicity
Fish
Crustacean
Algae
b. Persistence and degradability
Persistence
Degradability
LC 50 4~8mg/L 24hr
LC 50 3.5mg/L 48hr
N/A
N/A
N/A
5
c. Bio accumulative potential
Bioaccumulation
Biodegradability
d. Mobility in soil
BCF 60
73% 1day
N/A
e. Other adverse effects
N/A
13. Disposal consideration
Dispose of contents and container in accordance
with Waste Control Regulation
a. Disposal methods
14. Transport information
a. UN number
b. UN proper shipping name
c. Transport hazard classes
d. Packing group
e. Environmental hazards
f. Special precautions for a user
Extraordinary step in fire
Extraordinary step in spill
2586
ALKYLSULPHONIC ACIDS, LIQUID or
ARYLSULPHONIC ACIDS, LIQUID with not
more than 5% free sulphuric acid
8
Ⅲ
N/A
F-A
S-B
15. Regulatory information
a. N/A.
16. Other information
a. Reference
IUCLID Chemical Data Sheet, EC-ECB
TOXNET, U.S. National Library of Medicine(http://toxnet.nlm.nih.gov)
Corporate Solution From Thomson Micromedex(http://csi.micromedex.com)
ECOTOX Database, EPA(http://cfpub.epa.gov/ecotox)
ECB-ESIS(European chemical Substances Information System)(http://ecb.jrc.it/esis)
The Chemical Database, The Department of Chemistry at the University of
Akron(http://ull.chemistry.uakron.edu/erd)
International Chemical Safety Cards(ICSC)(http://www.nihs.go.jp/ICSC)
b. MSDS created
Revised.1
July 2010
May 2013
6
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