ELOTANT™ LS100 1. Chemical Product and Company Identification a. Product name ELOTANT LS100 Shampoo, soap, foam compositions, detergent raw materials b. Product use c. Company Identification LG Household & Healthcare Ltd. LG GwangHwaMoon Building, 92, Sinmunno 2ga,Jongno-gu, Seoul South Korea Zip Code 110062 Tel : 82-505-305-7007 e-mail : [email protected] Manufacturer Emergency phone number 2. Hazard Identification a. Classification of the substance or mixture Corrosive to metal: 1 category Acute toxicity : 4 category Skin corrosion/irritation : 2 category Serious eye damage/eye irritation : 1 category Skin sensitizer : 1 category Specific target organ toxicity following single exposure: 2 category b. GHS label elements, including precautionary statements Signal words Hazard statements Precautionary statements Prevention Danger H290 May be corrosive to metals H302 Harmful if swallowed H315 Causes skin irritation H317 May cause allergic skin reaction H318 Causes serious eye damage H371 May cause damage to organ P234 Keep only in original container P260 Do not breathe dust/fume/gas/mist/vapor/sprays. P261 Avoiding breathe dust/fume/gas/mist/vapor/sprays. 1 Response Storage Disposal c. Other hazards which do not result in classification Health Flammability Reactivity P264 Wash ….thoroughly after handling. P270 Do not eat, drink or smoke when using this product P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves, protective clothing, eye protection, fact protection P301+P312 If swallowed: Call a poison center or doctor/physician P302+P352 Gently wash with plenty of soap and water P305+P351+p338 If in eyes Rinse cautiously with water several minute P309+P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. P310 Immediately call a poison center or doctor/physician P321 Specific treatment (see…. On this label) P330 Rinse mouth P332+P313 If skin irritation occurs, get medical advice/ attention P333+P313 If skin irritation or rash occurs P405 Store locked up P501 Dispose of containers/containers to… 3 1 0 3. Composition/information on ingredients Component name CAS Number %(w/w) Dodecyl benzene Sulfonic acid 27176-87-0 96 % min Water 7732-18-5 2% max 4. First-aid measures a. Eye contact b. Skin contact c. Inhalation Wash Eyes Immediately With Large Amounts Of Water. Get medical attention immediately. Remove Contaminated Clothing Immediately. Wash with Soap or Mild Detergent and Large Amounts of Water Until No Evidence of Chemical Remains (At Least 15-20 Minutes). Remove Contaminated Clothing Immediately. Use a Bag Valve mask or Similar Device to Perform Artificial Respiration (Rescue Breathing) If Needed. Get Medical Attention Immediately. 2 d. Ingestion e. Further medical Contact Local Poison Control Center or Physician Immediately Give Large Amounts of Water. Allow Vomiting to Occur. N/A 5. Fire-fighting measures a. Suitable extinguishing media Suitable extinguishing media Large fire b. Specific hazards arising from the chemical Products of heat decomposition c. Special protective actions for fire-fighters CO2 Regular dry chemical Water Dry powder Fight larger fires with water spray or alcohol resistant foam Carbon oxide, Sulfur oxide Wear self contained breathing apparatus and protective gear. 6. Accidental release measures a. Personal precautions, protective equipment and emergency procedures b. Environmental precautions Air Soil underwater c. Methods and materials for containment and cleaning up Spill and releases Contain the spilled liquid with sand or an inert absorbent material. Avoid all possible sources of ignition (halogen, Spark, flame) Transfer used material to a suitable waste container and dispose of in accordance with local regulation. N/A N/A N/A Wash residue from spill area with water containing detergent and flush to a sewer serviced by a permitted wastewater treatment facility. 7. Handling and storage a. Precautions for safe handling b. Conditions for safe storage Normal precautions should be observed as for handling all chemicals. Store in the original closed containers under dry conditions. Keep way from incompatibles such as oxidizing agents, acids Avoid all possible sources of ignition (halogen, Spark, flame) 3 8. Exposure controls/personal protection a. Control parameters Internal regulation ACGIH Biological limit values b. Appropriate engineering controls c. Individual protection measures Respiratory protection Eye protection Protective gloves Skin protection N/A N/A N/A Provide exhaust ventilation. Other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Use vapor respirator Use goggles Wash eyes before breaks and at the end of work. Protective gloves Protective work clothing 9. Physical and chemical properties a. Appearance Physical state Color b. Odor c. Odor threshold d. pH e. Melting point/freezing point f. Initial boiling and boiling range g. Flash point h. Evaporation rate i. Flammability j. Upper/lower flammability k. Vapor pressure l. Solubility m. Vapor density n. Relative density o. Partition coefficient: n-octanol/water p. Auto-ignition temperature q. Decomposition temperature r. Viscosity s. Molecular weight Liquid Dark brown Special odor N/A 1~2 10℃ 315℃ 149℃ N/A N/A N/A N/A Soluble N/A 1.053 at 25 ℃ N/A N/A N/A 950 cps at 25 ℃ 326.54 4 10. Stability and Reactivity a. Chemical stability & Possibility of hazardous reactions b. Condition to avoid Stable in room temperature, no reaction. c. Incompatible materials Metals oxidizing materials, strong alkali, peroxide materials When combustion & burning, may occur irritations and harmful gas. d. Hazardous decomposition products 11. Toxicological information Avoid heat, flames, sparks and other sources of ignition a. Information on the likely routes of exposures Inhalation: N/A Acute: N/A Skin: N/A Eyes: N/A b. Symptoms related to physical, chemical and toxicological characteristics Acute toxicity Oral LD 50 650mg/kg Rat Thermal N/A Gases N/A Skin corrosion & irritation 2 Category Serious eye damage/eye irritation 1 Category Respiratory N/A Skin sensitization Slightly irritation Carcinogenicity IARC NTP OSHA WISHA ACGIH Germ cell mutagenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 12. Ecological information a. Eco toxicity Fish Crustacean Algae b. Persistence and degradability Persistence Degradability LC 50 4~8mg/L 24hr LC 50 3.5mg/L 48hr N/A N/A N/A 5 c. Bio accumulative potential Bioaccumulation Biodegradability d. Mobility in soil BCF 60 73% 1day N/A e. Other adverse effects N/A 13. Disposal consideration Dispose of contents and container in accordance with Waste Control Regulation a. Disposal methods 14. Transport information a. UN number b. UN proper shipping name c. Transport hazard classes d. Packing group e. Environmental hazards f. Special precautions for a user Extraordinary step in fire Extraordinary step in spill 2586 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid 8 Ⅲ N/A F-A S-B 15. Regulatory information a. N/A. 16. Other information a. Reference IUCLID Chemical Data Sheet, EC-ECB TOXNET, U.S. National Library of Medicine(http://toxnet.nlm.nih.gov) Corporate Solution From Thomson Micromedex(http://csi.micromedex.com) ECOTOX Database, EPA(http://cfpub.epa.gov/ecotox) ECB-ESIS(European chemical Substances Information System)(http://ecb.jrc.it/esis) The Chemical Database, The Department of Chemistry at the University of Akron(http://ull.chemistry.uakron.edu/erd) International Chemical Safety Cards(ICSC)(http://www.nihs.go.jp/ICSC) b. MSDS created Revised.1 July 2010 May 2013 6