MATERIAL SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: DOCUMENT IDENTIFIER: APPLICABLE CODES: SYNONYMS: CHEMICAL FAMILY NAME: NFPA HAZARD RATINGS(H-F-R): HMIS HAZARD RATINGS(H-F-R): DISTRIBUTOR: IN CASE OF EMERGENCY CALL: Ethylene glycol low-iron/low-chloride 01111 01111; 10000206; 10000207 1,2-Ethanediol; Ethylene alcohol; Glycol Glycol 2-1-0 2-1-0 HCI USA Distribution Companies 1-800-424-9300 MSDS PREPARED BY: HCI Technical Resource Center St. Louis, MO 63111 (314) 353-6500 2. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS Ethylene glycol CAS NUMBERS 000107-21-1 Percent 100 Trace impurities and additional material names not listed above may also appear in the Regulatory Information Section (Section 15) towards the end of the MSDS. These materials may be listed for local "Right to Know" compliance and for other reasons. 3. HAZARDOUS IDENTIFICATION EMERGENCY OVERVIEW:WARNING! May be irritating to eyes, skin, and respiratory tract. May be harmful if absorbed through skin. Harmful or fatal if swallowed. Inhalation of high concentrations may have narcotic effects. POTENTIAL HEALTH EFFECTS: SKIN Contact with the skin may cause irritation. CONTACT: SKIN This material is slightly toxic by dermal absorption. ABSORPTION: Contact with the eyes can cause moderate to severe irritation. EYES: INGESTION: Harmful or fatal if swallowed. Ingestion may cause nausea, vomiting, stomach pain, drowsiness, drunkenness, blindness, bluish skin color, lung congestion, convulsions or coma. May cause central nervous system depression. INHALATION: Inhalation of high concentrations may have narcotic effects. Inhalation of vapors may cause headache, dizziness, nausea, and loss of consciousness. This product does not contain any chemicals reportable under California Proposition 65. Components found on one of the OSHA designated carcinogen lists are listed below. INGREDIENT NTP IARC Ethylene glycol N N OSHA N 4. FIRST AID MEASURES SKIN CONTACT: EYE CONTACT: INGESTION: INHALATION: Remove contaminated clothing and shoes. Wash exposed areas with soap and water. Call a physician if irritation persists. Flush eyes with water for at least 15 minutes. Get immediate medical attention. Call a physician immediately! Give 2-3 (16 oz.) glasses of water. Induce vomiting. Do not give anything by mouth to an unconscious person. Remove to fresh air. If breathing has stopped, give artificial respiration. Give oxygen for breathing difficulty. Get medical attention. 5. FIRE FIGHTING MEASURES FIRE AND EXPLOSIVE PROPERTIES 241 oF FLASH POINT: 116.1 oC FLASH POINT: TCC FLASH POINT METHOD: LOWER FLAMMABILITY LIMIT: 3.2 UPPER FLAMMABILITY LIMIT: 15.3 AUTOIGNITION TEMPERATURE: 748 oF, 397.74 oC FLAMMABILITY IIIB CLASSIFICATION: Use water spray, carbon dioxide, dry chemical, or foam. EXTING. MEDIA: Water or foam may cause frothing. FIRE FIGHTING : Cool fire-exposed containers with water spray. Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Use NIOSH-approved self-contained breathing apparatus and complete PROTECTIVE EQUIPMENT: protective clothing when fighting chemical fires. Slight fire hazard. FIRE HAZARDS: During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. 6. ACCIDENTAL RELEASE MEASURES SMALL Contain spill and ventilate area. Absorb on inert media and containerize for disposal. SPILLS: LARGE Contain spill and ventilate area. Permit only trained personnel wearing full protective equipment to enter SPILLS: the spill area. Collect the spill in a waste container or remove with a vacuum truck. Prevent spill from entering natural watercourses. PROTECTIVE EQUIPMENT\ SPILL-RELEASE INSTRUCTIONS: Wear complete protective clothing when cleaning up chemical spills. Spills and releases may have to be reported to federal and/or local authorities. See the Regulatory Information section (section 14) regarding reporting requirements. 7. HANDLING AND STORAGE HANDLING: Avoid contact with skin, eyes, and clothing. Avoid breathing product vapors and mists. Do not take internally. Wash thoroughly after handling this material. Use this material only with adequate ventilation. STORAGE : Keep container closed when not in use. This material should be stored in a dry, cool place. Store in well ventilated areas and at moderate temperatures. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Good general ventilation (typically 10 air changes/hour) should be used. Ventilation rates should be matched to conditions. Use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. PERSONAL PROTECTIVE EQUIPMENT Wear protective gloves made of neoprene or rubber. SKIN: Wear chemical safety goggles. EYE : RESPIRATORY: If engineering controls do not maintain airborne concentrations below recommended limits, use a NIOSH-approved respirator for organic vapors. Emergency showers, eye-wash stations, and fire blankets should be accessible. Wear protective OTHER: clothing. EXPOSURE GUIDELINES : ACGIH ACGIH OSHA PEL OSHA STEL INGREDIENT STEL TLV Ethylene glycol N/EST N/EST N/EST N/EST See 29 CFR 1910.1000 (D) (2) and ACGIH "Threshold Limit Values for Chemical Substances and Physical Agents Biological Exposure Indices" booklet (Appendix C) for the determination of exposure limits for mixtures. Consult an industrial hygenist or similar professional to confrim that the calculated exposure limits are approriate. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: APPEARANCE ODOR: SPECIFIC GRAVITY: SOLUBILTY (IN WATER): BOILING POINT (oF): BOILING POINT (oC): FREEZING POINT (oF): FREEZING POINT (oC): MELTING POINT (oF): MELTING POINT (oC): PRODUCT pH : VAPOR PRESSURE: REFERENCE PRESSURE: Liquid Transparent colorless Mild sweet 1.115 Complete >387 197.22 8.6 -13 8.6 -13 Not available 0.06 mm Hg VAPOR DENSITY: REFERENCE DENSITY: EVAPORATION RATE: VISCOSITY: % VOLATILES: 2.1 Air=1 0.01 (Butyl acetate=1) Not available 100 10. STABILITY AND REACTIVITY Stable Keep away from heat, sparks, and open flames. Bases Acids Strong oxidizers Toxic oxides of carbon DECOMPOSITION: POLYMERIZATION WILL OCCUR: No STABILITY: CONDITIONS TO AVOID: INCOMPATIBILITY: 11. TOXICOLOGICAL INFORMATION IMMEDIATE EFFECTS: May be irritating to eyes, skin, and respiratory tract. May be fatal if swallowed. May have narcotic effects. IRRITATION DATA: 12 mg/kg eyes-rat; 555 mg open skin-rabbit mild; 500 mg/24 hours eyes-rabbit mild; 100 mg/1 hour eyes-rabbit moderate TOXICITY DATA: 15 gm/kg oral-man TDLo; 1195 mg/kg oral-man TDLo; 5500 mg/kg oral-child TDLo; 786 mg/kg oral-human LDLo; 398 mg/kg oral-human LDLo; 10000 mg/m3 inhalation-human TCLo; 16 gm/kg oral-man TDLo; 1637 mg/kg unreported-man LDLo; 4700 mg/kg oral-rat LD50; 10876 mg/kg inhalation-rat LC50; 5010 mg/kg intraperitonealrat LD50; 2800 mg/kg subcutaneous-rat LD50; 3260 mg/kg intravenous-rat LD50; 3300 mg/kg intramuscular-rat LDLo; 13 mg/kg unreported-rat LD50; 5500 mg/kg oral-mouse LD50; >200 mg/m3/2 hours inhalation-mouse LC; 5614 mg/kg intraperitoneal-mouse LD50; 2700 mg/kg subcutaneous-mouse LDLo; 3 gm/kg intravenous-mouse LD50; 8050 mg/kg unreported-mouse LD50; 5500 mg/kg oral-dog LD50; 1650 mg/kg oral-cat LD50; 2 intraperitoneal-rabbit LDLo; 9530 ul/kg skin-rabbit LD50; 1mg/kg intramuscular-rabbit LDLo; 5 gm/kg unreported-rabbit LD50; 6610 mg/kg oral-guinea pig LD50; 5 gm/kg subcutaneous-guinea pig LDLo; 11150 mg/kg unreported-guinea pig LD50; 438 mg/kg/2 years continuous oral-rat TDLo; 85230 mg/kg/90 days continuous oral-rat TDLo; 12 ml/kg/6 days intermittent oral-rat TDLo; 26150 mg/kg/2 years continuous oral-rat TDLo; 8400 ug/kg/24 hours 12 week continuous inhalation-rat TCLo; 12 mg/m3/8 hours- 90 days intermittent inhalation-rat TCLo; 1 gm/m3/32 weeks intermittent inhalation-rat TCLo; 546 gm/kg/13 weeks continuous oral-mouse TDLo; 1081 gm/kg/2 years continuous oralmouse TDLo; 5751 gm/kg/22 weeks intermittent oral-monkey TDLo; 12 mg/m3/8hours 90 days intermittent inhalation-rabbit TCLo CARCINOGENICITY: CARCINOGEN STATUS: A4 - Not Classifiable as a Human Carcinogen MUTAGENICITY: MUTAGENIC DATA: DNA inhibition - human lymphocyte 320 mmol/L; cytogenetic analysis - rat oral 1200 mg/kg; mutation in mammalian somatic cells - mouse lymphocyte 100 mmol/L No data available EPIDEMIOLOGY: TERATOGENICITY: No data available REPRODUCTIVITY: REPRODUCTIVE EFFECTS DATA: 50 gm/kg oral-rat TDLo 6-15 days pregnant female continuous; 8580 mg/kg oral-rat TDLo 6-15 days pregnant female comtinuous; 12500 mg/kg oral-rat TDLo 6-15 days pregnant female continuous; 25 gm/kg oral-rat TDLo 6-15 days pregnanat female continuous; 50 gm/kg oral TDLo 6-15 days pregnant female continuous; 2500 mg/m3 inhalation-rat TCLo/6 hours 6-15 days pregnant female continuous; 7500 mg/kg oral-mouse TDLo 6-15 days pregnant female continuous; 84 gm/kg oral-mouse TDLo 1-21 days pregnant female/21 days post pregnancy contiuous; 88720 mg/kg oral-mouse TDLo 7-14 days pregnant female continuous; 15 gm/kg oralmouse TDLo 6-15 days pregnant female continuous; 1000 mg/m3 inhalation-mouse TCLo/6 hours 6-15 days pregnant female contnuous; 2100 mg/m3 inhalation-mouse TCLo/6 hours 6-15 days pregnant continuous; 2100 mg/m3 inhalation-mouse TCLo/6 hours 6-15 days pregnant female continuous; 28 gm/kg oral-rabbit TDLo 6-19 days pregnant female continuous NEUROTOXICITY: OTHER EFFECTS: No data available No data available 12. ECOLOGICAL INFORMATION ECOTOXICITY DATA: FISH TOXICITY: >10000000 ug/L 96 hours LC50 (Mortality) Fathead minnow (Pimephales promelas) INVETABRATE TOXICITY: >100000 ug/L 28 hours LC50 (Mortality) Common shrimp (Crangon crangon) ALGAL TOXICITY: 112000 ug/L 48 hours (Population Growth) Cryptomonad (Chilomonas paramecium) OTHER TOXICITY: 326000 ug/L 48 hours LC50 (Mortality) Clawed toad (Xenopus laevis) 13. DISPOSAL CONSIDERATIONS RCRA No WASTE: RCRA ID Not applicable NUMBER: VOC 100% @ 9.308 CONTENT (lbs/gal): Waste Disposal Discharge, treatment, or disposal may be subject to Federal, State, or Local laws. State and Local regulations and restrictions are complex and may differ from Federal disposal regulation. The Procedure: information offered here is for the product as shipped. Use and/or alterations to the product such as mixing with other materials may significantly change the characteristics of the material and alter the RCRA Classification and the proper disposal method. 14. TRANSPORTATION INFORMATION D.O.T. SHIPPING NAME: D.O.T. HAZARD CLASS: DOT ID NUMBER: DOT PACKING GROUP: DOT RQ (lbs): CONTRIBUTING CHEMICAL: OTHER: MARINE POLLUTANT: Environmentally hazardous substances, liquid, n.o.s. (Ethylene glycol) Class 9, No division Miscellaneous hazardous materials UN 3082 III 5000 Ethylene glycol Shipments of this product are not regulated when shipped in quantities below the RQ. No INTERNATIONAL REGULATORY INFORMATION IMDG HAZARD CLASS: ICAO HAZARD CLASS: 9 - Miscellaneous dangerous substance and articles 9 - Class 9 Label 15. REGULATORY INFORMATION FEDERAL REGULATIONS TSCA (Toxic Substance Control Yes Act): SECTION 311/312 HAZARD Immediate (Acute) health hazard, Delayed (Chronic) health hazard CLASS: SARA TITLE III (Superfund Amendments and Reauthorization Act): INGREDIENTS CAS NUMBERS Ethylene glycol 000107-21-1 WHMIS CLASSIFICATION (CANADA): FOREIGN INVENTORY: Section 313 Y Section 302 N No data available EINECS (European Inventory of Existing Commercial Chemical Substances) Canadian DSL (Domestic Substances List) STATE RIGHT TO KNOW CALIFORNIA PROP 65 This product does not contain any chemicals reportable under California Proposition 65. MASSACHUSETTS SUBSTANCE LIST: Ethylene glycol NEW JERSEY SUBSTANCE LIST: Ethylene glycol PENNSYLVANIA HAZARDOUS SUBSTANCE LIST: Ethylene glycol 16. OTHER INFORMATION 04/22/1997 CREATION DATE: 10/24/2000 REVISION DATE: DISCLAIMER: The information herein is presented in good faith and is believed to be correct as of the date hereof. However, HCI makes no representation as to the completeness and accuracy thereof. Users must make their own determination as to the suitability of the product for their purposes prior to use. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature with respect to the product or to the information herein is made hereunder. HCI shall in no event be responsible for any damages of whatsoever nature directly or indirectly resulting from the publication, or use of, or reliance upon the information contained herein. EXPLANATION OF ABBREVIATIONS: N/EST = Not Established N/AP = Not Applicable N/AV = Not Available Material Safety Data Sheet Revision Date: 04/11/2006 Issue date: 04/11/2006 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: C5-A Copper Anti-Seize Stick Product type: Lubricant Company address: Henkel Corporation 1001 Trout Brook Crossing Rocky Hill, Connecticut 06067 Item No. : 37229 Region: United States Contact Information: Telephone: 860.571.5100 Emergency telephone: 860.571.5100 Internet: www.loctite.com 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Petroleum Distillates Proprietary % 30-60 Copper 7440-50-8 10-30 Graphite 7782-42-5 10-30 Silica, quartz 14808-60-7 ACGIH TLV 5 mg/m³ TWA (mist) 10mg/m³ STEL (mist) OSHA PEL 5 mg/m³ TWA (mist) 0.2 mg/m³ TWA fume 0.1 mg/m³ TWA fume 1 mg/m³ TWA dust and 1 mg/m³ TWA dusts and mist, as Cu mists 2 mg/m³ TWA respirable 15 mg/m³ (total), 5 mg/m³ fraction, all forms except (respirable) graphite fibers 0.05 mg/m³ TWA 0.1mg/m³ TWA respirable fraction (respirable) 1-5 OTHER None None None None 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Color: Odor: Solid Copper Mild petroleum CAUTION: HEALTH: FLAMMABILITY: PHYSICAL HAZARD: Personal Protection: 1 1 0 See Section 8 MAY CAUSE EYE AND SKIN IRRITATION. Relevant routes of exposure: Skin, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: This product has low volatility and is not expected to cause respiratory tract irrritation during normal conditions of use. May cause respiratory tract irritation. Inhalation of copper fumes may result in metal fume fever. Symptoms include metallic taste, discoloration of skin or hair. Prolonged or repeated contact may cause irritation. Contact with eyes will cause irritation. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Principal hazard of ingestion is aspiration into the lungs and subsequent pneumonitis. Eye, skin, and respiratory disorders. See Section 11 for additional toxicological information. Item No. : 37229 Product name: C5-A Copper Anti-Seize Stick 1 of 5 4. FIRST AID MEASURES Inhalation: Remove to fresh air. If discomfort persists seek medical attention. Skin contact: Wash with soap and water. Get medical attention if symptoms develop and persist. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Aspiration may cause pulmonary edema and pneumonitis. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Flash point: Not applicable Product is a solid. Burn Rate: Approx 14mm/2 minutes Autoignition temperature: Not determined Flammable/Explosive limits-lower %: Not determined Flammable/Explosive limits-upper %: Not determined Extinguishing media: Carbon dioxide (CO2). Dry chemical. Foam. Special fire fighting procedures: None Unusual fire or explosion hazards: None Hazardous combustion products: Oxides of carbon. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: No special environmental precautions required. Clean-up methods: Scrape up as much material as possible. Clean residue with soap and water. Dispose of in accordance with local and national regulations. 7. HANDLING AND STORAGE Handling: Keep container closed. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Storage: Keep in a cool, well ventilated area. Incompatible products: Oxidizing agents. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Ensure adequate ventilation. Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Observe OSHA regulations for respiratory use (29 CFR 1910.134). Skin protection: Cover as much of the exposed skin area as possible with appropriate clothing. Eye/face protection: Safety glasses with side-shields. Goggles. Item No. : 37229 Product name: C5-A Copper Anti-Seize Stick 2 of 5 See Section 2 for exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Vapor pressure: pH: Boiling point/range: Melting point/range: Specific gravity: Vapor density: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Solid Copper Mild petroleum Not determined Not applicable Not available Not available 1.18 Not determined Not determined Insoluble Not determined 13.0%; 153 grams/liter 10. STABILITY AND REACTIVITY Stability: Stable at normal conditions Hazardous polymerization: Will not occur. Hazardous decomposition products: Oxides of carbon. Incompatability: Oxidizing agents. Conditions to avoid: None known. 11. TOXICOLOGICAL INFORMATION Carcinogen Status Hazardous components Petroleum Distillates Proprietary Copper 7440-50-8 Graphite 7782-42-5 Silica, quartz 14808-60-7 NTP Carcinogen No IARC Carcinogen No OSHA Carcinogen No No No No No No No Known Carcinogen Group 1 Yes Literature Referenced Target Organ & Other Health Effects Hazardous components Petroleum Distillates Proprietary Copper 7440-50-8 Graphite 7782-42-5 Silica, quartz 14808-60-7 Health Effects/Target Organs Irritant Skin, Sensory, Mutagen, Liver, Kidney, Irritant, Immune system, Gastrointestinal, Central nervous system, Blood, Allergen, Developmental Lung Some evidence of carcinogenicity, Lung, Immune system 12. ECOLOGICAL INFORMATION Ecological information: Item No. : Not available 37229 Product name: C5-A Copper Anti-Seize Stick 3 of 5 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations. EPA hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR): Proper shipping name: Unrestricted Hazard class or division: None Identification number: None Packing group: None DOT reportable quantity (lbs): Copper (CAS# 7440-50-8) is reportable at 5000 pounds (2700kg) Marine pollutant: Copper International Air Transportation (ICAO/IATA): Proper shipping name: Unrestricted Hazard class or division: None Identification number: None Packing group: None WaterTransportation (IMO/IMDG): Proper shipping name: Hazard class or division: Identification number: Packing group: Marine pollutant: Environmentally hazardous substances, solid, n.o.s. (Copper) 9 UN3077 III Copper 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None. CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: None. Immediate Health Hazard This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Copper (CAS# 7440-50-8). California Proposition 65: No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: Item No. : All components are listed on or are exempt from listing on the Domestic Substances List. D.2.A, D.2.B 37229 Product name: C5-A Copper Anti-Seize Stick 4 of 5 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Prepared by: C.J. Michaels, Senior Product Safety & Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Item No. : 37229 Product name: C5-A Copper Anti-Seize Stick 5 of 5