TABLA ENTALPIA,ENTROPIA,ENERGIA LIBRE

AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
FISICOQUIMICA
MAGNITUDES TERMODINÁMICAS PARA SUSTANCIAS E IONES A 25º C
SUSTANCIA
e - (g)
H + (g)
H + (ac)
H(g)
H2(g)
∆H O ( KJ / mol )
∆G O ( KJ / mol )
S O ( J / mol − K )
0
1536.3
0
218.0
0
0
1517.1
0
203.30
0
20.87
108.83
0
114.60
130.6
687.163
-278.46
161
0
-616.9
-408
-351
-270
609.839
-239.66
107.76
0
-575.4
-411.1
-361
-288
-947.7
-1130.8
514.197
-251.2
89.2
0
-568.6
-436.68
-394
-328
495.04
-246
85.81
0
-549.28
-430.58
-389.2
-328
458.5
-248
76.7
0
-554.7
-442.8
-395
-337
649.989
-293.8
128
0
-558.7
-384
-342
-270
574.877
-261.87
77.299
0
-545.1
-384.0
-349
-285
-851.9
-1048.1
481.202
-282.28
60.7
0
-538.9
-408.8
-380
-323
-282.2
55.86
0
132.91
14
138.67
29.10
35.66
59.30
74.1
85.8
147.85
60.2
153.61
51.446
51.21
72.12
86.82
98.5
102
139
154.47
103
160.23
64.672
66.55
82.55
95.94
106.39
124
169.99
69.5
-378.1
-326
427.1
-282.0
49.7
0
-525.4
-414
-383
-333
108.3
118.0
169.72
133
175.5
85.15
88
101.18
121
130
Grupo IA
Li + (g)
Li + (ac)
Li (g)
Li (s)
LiF (s)
LiCI (s)
LiBr (s)
Li I (s)
Na + (g)
Na + (ac)
Na (g)
Na (s)
NaF (s)
Na Cl (s)
Na Br (s)
Na I (s)
Na HCO 3 (s)
Na 2 CO 3 (s)
K + (g)
K+ (ac)
K (g)
K(s)
KF (s)
KCI (s)
KBr (s)
KI (s)
Rb + (g)
Rb + (ac)
Rb +(g)
Rb +(s)
Rb F(s)
Rb CI(s)
Rb Br(s)
Rb I(s)
Cs + (g)
Cs + (ac)
Cs +(g)
Cs +(s)
Cs F(s)
Cs CI(s)
Cs Br(s)
Cs I(s)
Grupo IIA
Mg 2+ (g)
2351
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
FISICOQUIMICA 1
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
Mg 2+(ac)
Mg + (g)
Mg (g)
Mg (s)
Mg CI2 (s)
Mg O (s)
Mg 3 N2 (s)
Mg CO3 (s)
Ca2+ (g)
Ca 2+(ac)
Ca + (g)
Ca (g)
Ca (s)
Ca F2 (s)
Ca CI2 (s)
Ca O (s)
Ca CO3 (s)
Ca SO4 (g)
Ca3(PO4) 2 (s)
Sr2+ (g)
Sr 2+(ac)
Sr+ (g)
Sr (g)
Sr (s)
Sr CI2 (s)
Sr O (s)
Sr CO3 (s)
Sr SO4 (s)
Ba 2+(g)
Ba 2+ (ac)
Ba+ (g)
Ba (g)
Ba (s)
BaCI 2 (s)
Ba O (s)
Ba CO3 (s)
Ba SO4(s)
FISICOQUIMICA
-456.01
-118
115
0
-592.1
-569.0
-401
-1028
148.55
32.69
89.630
26.9
88
65.86
-553.04
-55.2
158.9
0
-1162
-750.2
-603.5
-1128.8
-1320.3
-3899
154.78
41.6
68.87
114
38.2
92.9
107
263
-557.3
-39
110
0
-781.2
-562.4
-1138
-1334
164.54
54.4
117
55.5
97.1
122
-560.7
13
144.8
0
-810.9
-520.4
-1139
-1353
170.28
62.5
126
72.07
112
132
0
-1272
0
-524.7
-1676
0
-1193
0
-481.2
-1582
5.87
53.8
28.3
-313
50.94
715.0
0
1.896
-110.5
-393.5
412.9
-676.26
-691.11
669.6
0
2.866
137.2
-394.4
-386.2
-528.10
-587.06
158.0
5.686
2.439
197.5
213.7
121
-53.1
95.0
-461.96
894.1
150
0
-641.6
-601.2
-461
-1112
1934.1
-542.96
788.6
192.6
0
-1215
-795.0
-635.1
-1206.9
-1432.7
-4138
1784
-545.51
719.6
164
0
-828.4
-592.0
-1218
-1445
1649.9
-538.36
684.6
175.6
0
-806.06
-548.1
-1219
-1465
Grupo IIIA
B ((b) – romboédrico)
B2O2(s)
Al (s)
Al3+Cac)
Al2O3(s)
Grupo IVA
C(g)
C(grafito)
C (diamantes)
CO(g)
CO2(g)
CO2 (ac)
CO32-(ac)
HCO3 – (ac)
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
FISICOQUIMICA 2
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
H2CO3(ac)
CH4(g)
C2H2 (g)
C2H4 (g)
C2H6 (g)
C6H6 (l)
CH3OH(g)
CH3OH (l)
HCHO(g)
HCOO- (a)
HCOOH (l)
HCOOH (ac)
C2H5 OH (l)
CH3 CHO (g)
CH3 COOH (l)
CN- (ac)
HCN(g)
HCN(l)
HCN(ac)
CS2 (g)
CS 2 (l)
CH3 CI (g)
CH2Cl2 (l)
CHCl3 (l)
CCI4 (g)
CCI4 (l)
COCI2 (g)
Si (s)
SiO2 (s)
Sn (gris)
Sn (blanco)
Sn Cl4 (l)
Pb2+ (ac)
Pb (s)
PbO (s, rojo)
PbO2(s)
PbS(s)
PbCl2(s)
PbSO4(s)
FISICOQUIMICA
-698.7
-74.87
227
52.47
-84.667
49.0
-201.2
-238.6
-116
-410
-409
-410
-277.63
-166
-487.0
151
135
105
105
117
87.9
-83.7
-117
-132
-96.0
-139
-220
0
-910.9
3
0
-545.2
1.6
0
-219.0
-276.6
-98.3
-359
-918.39
-623.42
-50.81
209
68.36
-32.89
124.5
-161.9
-166.2
-110
-335
-346
-356
-174.8
-133.7
-392
166
125
121
112
66.9
63.6
-60.2
-63.2
-71.5
-53.7
-68.6
-206
0
-86.5
4.6
0
-474.0
-24.3
0
-189.2
-219.0
-96.7
-314
-811.24
191
186.1
200.85
218.22
229.5
172.8
238
127
219
91.6
129.0
164
161
266
160
118
201.7
112.8
129
237.79
151.0
234
179
203
309.7
214.4
283.74
18.0
41.5
44.8
51.5
259
21
64.785
66.5
76.6
91.3
136
147
473
0
90.29
33.2
9.16
11
-45.9
-80.83
-206.57
-173.23
-206.57
-365.6
333.9
0
69.8
146.2
456
0
86.60
51
97.7
118
-16
26.7
-110.5
-79.914
-110.5
-184.0
292.0
0
48.0
103.8
153.2
191.5
210.65
239.9
304.3
346
193
110
146
155.6
146
151.1
163.1
22.8
164
218.0
Grupo VA
N(g)
N2(g)
NO(g)
NO2(g)
N2O4(g)
N2O5(g)
NH3(g)
NH3(ac)
NO3-(ac)
HNO3(l)
HNO3(ac)
NH4NO3(s)
P (g)
P(rojo)
P4(blanco)
P2(g)
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
FISICOQUIMICA 3
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
P4(g)
PCl5(g)
P4O10(s)
PO43-(ac)
HPO42-(ac)
H2PO4 –(ac)
H3PO4(ac)
FISICOQUIMICA
128.9
-287
-343
-2940
-1277
-1292.1
-1296.3
-1288.3
72.4
-267.8
-278
-2675
-1018
-1089.3
-1130.4
-1142.7
128.9
311.7
364.5
228.9
-222
-33
90.4
158
249.2
0
143
-229.94
-241.826
-285.840
-187.8
-191.2
279
129
101
0
0.30
41.8
-17.7
-20.2
-39
-296.8
-396
-907.51
-885.75
-813.989
-907.51
231.7
0
163
-157.30
-228.60
-237.192
-120.4
-134.1
239
80.1
49.1
0
0.096
83.7
12.6
-33
-27.4
-300.2
-371
-741.99
-752.87
-690.059
-741.99
160.95
205.0
238.82
-10.54
188.72
69.940
110
144
168
228.1
430.211
31.9
32.6
22
61.1
205.6
122
248.1
256.66
17
126.9
156.90
17
78.9
-255.6
-329.1
0
-273
121.0
-234
-167.46
0
-92.31
-167.46
111.9
-218.9
-120.9
30.91
0
-36
106.8
-194.7
-55.94
61.8
-262.5
-276.5
0
-275
105.0
-240
-131.17
0
-95.30
-131.17
82.40
158.64
145.47
-9.6
202.7
173.67
165.1
153.25
55.10
223.0
186.79
55.06
174.90
-102.82
3.13
0
-53.5
70.21
80.71
245.78
152.23
198.59
180.67
-51.67
109.4
Grupo VIA
O(g)
O2(g)
O3(g)
OH-(ac)
H2O(g)
H2O(l)
H2O2(l)
H2O2(ac)
S(g)
S2(g)
S8(g)
S (rómbico)
S(monoclínico)
S2-(ac)
HS-(ac)
H2S-(g)
H2S(ac)
SO2(g)
SO3(g)
SO42-(ac)
HSO4-(ac)
H2SO4(l)
H2SO4(ac)
Grupo VIIA
F(g)
F-(g)
F-(ac)
F2(g)
HF(g)
Cl(g)
Cl-(g)
Cl-(ac)
Cl2(g)
HCl(g)
HCl(ac)
Br(g)
Br -(g)
Br -(ac)
Br2(g)
Br2(l)
HBr(g)
I(g)
I-(g)
I-(ac)
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
FISICOQUIMICA 4
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
FISICOQUIMICA
62.442
0
25.9
19.38
0
1.3
260.58
116.14
206.33
51.9
64.39
341.1
0
105.9
289.2
0
-203
-127.03
-99.50
-62.38
-31.8
50.2
64.98
301.4
0
77.111
250.4
0
-185
-109.72
-95.939
-66.32
-40.3
-26
-98.7
166.29
33.1
73.93
172.892
42.702
84
96.11
107.1
114
146
-152.4
130.5
0
-348.0
-203
-72.38
112.8
0
-144
-106.5
160.9
41.6
43.9
57.7
-61.1
167.64
51.5
71
61.30
0
-230
-264.9
-90.79
-147.21
94.93
0
-318.2
-198
-77.74
78.20
0
-141
164.8
153.9
31.8
0
-184
-210.66
-58.50
174.87
76.027
144
196
70.27
-1971
0
-863.2
-1461
0
-706
-1257
23.8
38
214
Mn2+(ac)
Mn(s,a)
MnO2 (s)
MnO4 –(ac)
-219
0
-520.9
-518.4
-223
0
-466.1
-425.1
-84
31.8
53.1
190
Grupo VIIIB
Fe3+(ac)
Fe2+(ac)
Fe(s)
Fe(l)
-47.7
-87.9
0
13.13
-10.5
-84.94
0
11.05
-293
113
27.3
34.29
I2(g)
I2(s)
HI(g)
Grupo IB
Cu+(ac)
Cu2+(ac)
Cu(g)
Cu(s)
Ag+(ac)
Ag(g)
Ag(s)
AgF(s)
AgCl(s)
AgBr(s)
AgI(s)
Ag2S(s)
Grupo IIB
Zn2+(ac)
Zn(g)
Zn(s)
ZnO(s)
ZnS(s, blenda de zinc)
Cd2+(ac)
Cd(g)
Cd(s)
CdS(s)
Hg2+(ac)
Hg22+(ac)
Hg(g)
Hg(l)
HgCl2(s)
Hg2Cl2(s)
HgO(s)
Grupo VIB
(Cr ( H2O)6)3+(ac)
Cr(s)
CrO42-(ac)
Cr2O72-(ac)
Grupo VIIB
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
FISICOQUIMICA 5
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
-272.0
-825.5
-1121
-67.4
0
-64.0
0
FeO(s)
Fe2O3(s)
Fe3O4(s)
Co2+(ac)
Co(s)
Ni2+(ac)
Ni(s)
FISICOQUIMICA
-251.4
-743.6
-1018
-51.5
0
-46.4
0
60.75
87.400
145.3
-155
30
-159
30.1
CAPACIDADES CALORÍFICAS MOLARES DE GASES A PRESIÓN CONSTANTE
(De acuerdo a la expresión Cp = a + bT cT2 )
(Válidas para temperaturas entre 300 – 1500 K)
cal/K-mol
H2
O2
N2
Cl2
CO
CO2
H2O(v)
NH3
SO2
CH4
C2H6
C2H4
Cp
Cp
Cp
Cp
Cp
Cp
Cp
Cp
Cp
Cp
Cp
Cp
=
=
=
=
=
=
=
=
=
=
=
=
6.947
6.148
6.524
7.576
6.420
6.214
7.256
6.189
6.147
3.381
2.247
2.830
–
–
–
–
–
–
–
–
–
–
–
–
0.00020T +
0.00310T 0.00125T 0.00242T 0.00167T 0.0104T
–
0.00230T +
0.00789T 0.0138T
0.0180T
0.0382T
0.0286T
+
0.48 ∗ 10-6 T2
0.92 ∗ 10-6 T2
0.001 ∗ 10-6 T2
0.97 ∗ 10-6 T2
0.196 ∗ 10-6 T2
3.55 ∗ 10-6 T2
0.28 ∗ 10-6 T2
0.73 ∗ 10-6 T2
9.10 ∗ 10-6 T2
4.30 ∗ 10-6 T2
11.05 ∗ 10-6 T2
8.73 ∗ 10-6 T2
PRESIÓN DE VAPOR DEL AGUA
Temperatura (oC)
Presión (mmHg)
Temperatura (oC)
Presión (mmHg)
0
5
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
4.6
6.5
9.2
9.8
10.5
11.2
12.0
12.8
13.6
14.5
15.5
16.5
17.5
18.7
19.8
21.1
22.4
23.8
25.2
27
28
29
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
26.7
28.3
30.0
31.8
42.2
55.3
71.9
92.5
118.0
149.4
187.5
233.7
289.7
355.1
433.6
525.8
633.9
760.0
906.1
AUXILIAR DE DOCENCIA: Univ. Miguel Angel Gutierrez
FISICOQUIMICA 6