Supporting Information Critical Analysis of the Crystal Orientation

Supporting Information
Critical Analysis of the Crystal Orientation Behavior in Polyethylene-based
Crystalline-Amorphous Diblock Copolymer
Ming-Champ Lin1, Yi-Chin Wang1, Hsin-Lung Chen1*, Alejandro J. Müller2,
Chun-Jen Su3 and U-Ser Jeng3
1
2
Department of Chemical Engineering, National Tsing Hua University, Hsin-Chu 30013, Taiwan;
Departamento de Ciencia de los Materiales, Grupo de Polímeros USB, Apartado 89000-A, Caracas, Venezuela;
3
National Synchrotron Radiation Research Center, Hsin-Chu 300, Taiwan
Figure S1. The 2D SAXS/WAXD patterns of shear-oriented PE-b-PDLLA after crystallization at indicated Tcs.
(1)-(11) tangential-view SAXS pattern; (12)-(22) tangential-view WAXD pattern; (23)-(33) top-view SAXS
pattern; (34)-(44) top-view WAXD pattern.
Tc = 102 oC
(1)
(12)
qy
qy
qy
1 2 3
qz
qz
(23)
(200)
(110)
(34)
qy
qx
qx
Tc = 80 oC
(2)
(13)
qy
qy
(24)
qy
qz
qz
(35)
qy
qx
qx
Tc = 70 oC
(3)
(14)
qy
qy
qz
(25)
qy
qz
(36)
qy
qx
qx
Tc = 60 oC
(4)
(15)
qy
qy
(26)
qy
qz
qz
(37)
qy
qx
qx
Tc = 45 oC
(5)
(16)
qy
qy
(27)
qy
qz
qz
(38)
qy
qx
qx
Tc = 30 oC
(6)
(17)
qy
qy
qz
(28)
qy
qz
(39)
qy
qx
qx
Tc = 10 oC
(7)
(18)
qy
qy
qy
(29)
qy
qx
qz
qz
(40)
qx
Tc = -10 oC
(8)
(19)
qy
qy
(30)
qy
qz
qz
(41)
qy
qx
qx
Tc = -30 oC
(9)
(20)
qy
qy
qz
(31)
qy
qz
(42)
qy
qx
qx
Tc = -50 oC
(10)
(21)
qy
qy
(32)
qy
qz
qz
(43)
qy
qx
qx
Tc = Liquid Nitrogen
(11)
(22)
qy
qy
qz
(33)
qy
qz
(44)
qy
qx
qx